Issue 33, 2012
From the journal:

Chemical Communications

Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites†

Mario Carrasco,a   Michelle Faust,b   Riccardo Peloso,a   Amor Rodríguez,a   Joaquín López-Serrano,a   Eleuterio Álvarez,a   Celia Maya,a   Philip P. Power*b  and  Ernesto Carmona*a  

* Corresponding authors

a Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica, Universidad de Sevilla-Consejo Superior de Investigaciones Científicas, Avenida Américo Vespucio 49, 41092 Sevilla, Spain
E-mail: guzman@us.es
Fax: +34-954460565

b Department of Chemistry, University of California, One Shields Avenue, Davis, USA
E-mail: pppower@ucdavis.edu

Abstract

New quadruply bonded dimolybdenum complexes of the terphenyl ligand ArXyl2 (ArXyl2 = C6H3-2,6-(C6H3-2,6-Me2)2) have been prepared and structurally characterized. The steric hindrance exerted by the ArXyl2 groups causes the Mo atoms to feature unsaturated four-coordinate structures and a formal fourteen-electron count.

Graphical abstract: Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

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Article information

DOI
https://doi.org/10.1039/C2CC30394A
Article type
Communication
Submitted
17 Jan 2012
Accepted
25 Feb 2012
First published
28 Feb 2012

Chem. Commun., 2012,48, 3954-3956

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Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

M. Carrasco, M. Faust, R. Peloso, A. Rodríguez, J. López-Serrano, E. Álvarez, C. Maya, P. P. Power and E. Carmona, Chem. Commun., 2012, 48, 3954 DOI: 10.1039/C2CC30394A

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