Rationalizing the F⋯S interaction discovered within a tetrafluorophenylazido-containing bola-phospholipid

Yi Xia; Stéphane Viel; Yang Wang; Fabio Ziarelli; Erik Laurini; Paola Posocco; Maurizio Fermeglia; Fanqi Qu; Sabrina Pricl; Ling Peng

doi:10.1039/C2CC18147A

Rationalizing the F⋯S interaction discovered within a tetrafluorophenylazido-containing bola-phospholipid†

Yi Xia,^ab Stéphane Viel,^c Yang Wang,^a Fabio Ziarelli,^d Erik Laurini,^e Paola Posocco,^e Maurizio Fermeglia,^e Fanqi Qu,^b Sabrina Pricl^e and Ling Peng*^a

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* Corresponding authors

^a Aix-Marseille Université, CNRS CINaM UMR 7325, Marseille, France
E-mail: ling.peng@univmed.fr
Tel: +33 4918 29154

^b College of Chemistry and Molecular Sciences, Wuhan University, China

^c Aix-Marseille Université, Institut de Chimie Radicalaire, Marseille, France

^d Aix-Marseille Université, Spectropole, Marseille, France

^e Molecular Simulation Engineering Laboratory, Trieste University, Italy

Abstract

A bola-lipid bearing tetrafluorophenylazido chromophore in the diacyl chain displayed puzzling ¹⁹F NMR, leading to the evidence and rationalization of a F⋯S weak interaction that is important for altering molecular structures and imposing novel and special properties on fluorinated compounds.

Chemical Communications

Rationalizing the F⋯S interaction discovered within a tetrafluorophenylazido-containing bola-phospholipid†

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Rationalizing the F⋯S interaction discovered within a tetrafluorophenylazido-containing bola-phospholipid

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