Issue 19, 2012
From the journal:

Chemical Communications

Iron-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to α-olefins†

Shinji Maetani,a   Takahide Fukuyama,*a   Nobuyoshi Suzuki,b   Daisuke Ishiharab  and  Ilhyong Ryu*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka, Japan
E-mail: fukuyama@c.s.osakafu-u.ac.jp, ryu@c.s.osakafu-u.ac.jp
Fax: +82-72-254-9695
Tel: +81-72-254-9695

b Kao Corporation, Wakayama, Wakayama, Japan

Abstract

The catalytic decarbonylation reaction of aliphatic carboxylic acids can be carried out in the presence of an iron complex, and it proceeds smoothly to give α-olefins with high selectivity.

Graphical abstract: Iron-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to α-olefins

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Article information

DOI
https://doi.org/10.1039/C2CC18093F
Article type
Communication
Submitted
27 Dec 2011
Accepted
09 Jan 2012
First published
10 Jan 2012

Chem. Commun., 2012,48, 2552-2554

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Iron-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to α-olefins

S. Maetani, T. Fukuyama, N. Suzuki, D. Ishihara and I. Ryu, Chem. Commun., 2012, 48, 2552 DOI: 10.1039/C2CC18093F

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