Issue 19, 2012
From the journal:

Chemical Communications

One unprecedented 1-D europium thioindate-thioantimonate based on heterometallic mixed nitro-thioclusters with photoluminescent properties†

Jian Zhou,*a   Litao An,b   Xing Liu,a   Huahong Zou,c   Feilong Hua  and  Chaomin Liua  

* Corresponding authors

a College of Chemistry and Material, Yulin Normal University, Yulin 537000, P.R. China
E-mail: Jianzhou888888@163.com, Jianzhou888888@yahoo.com.cn
Fax: +86-775-2622315
Tel: +86-775-2622315

b College of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian 223300, P.R. China

c School of Chemistry and Chemical Engineering of Guangxi Normal University, Guilin 541004, P.R. China

Abstract

One novel 1-D europium thioindate-thioantimonate {[Eu(tepa)]2[μ2-SbS3](μ2-H2O)}[Eu(tepa)In4S9]·0.25tepa (1, tepa = tetraethylenepentamine) has been solvothermally synthesized. 1 represents the first example of the coordination of a soft Lewis basic 1-D polymeric [In4S96−]n ligand to a hard Lewis acidic Eu3+ ion. The wide-band-gap semiconductor and photoluminescence properties of 1 have been investigated.

Graphical abstract: One unprecedented 1-D europium thioindate-thioantimonate based on heterometallic mixed nitro-thioclusters with photoluminescent properties

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Article information

DOI
https://doi.org/10.1039/C2CC17899K
Article type
Communication
Submitted
18 Dec 2011
Accepted
05 Jan 2012
First published
10 Jan 2012

Chem. Commun., 2012,48, 2537-2539

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One unprecedented 1-D europium thioindate-thioantimonate based on heterometallic mixed nitro-thioclusters with photoluminescent properties

J. Zhou, L. An, X. Liu, H. Zou, F. Hu and C. Liu, Chem. Commun., 2012, 48, 2537 DOI: 10.1039/C2CC17899K

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