Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

Thorsten Gehrmann; Matthias Kruck; Hubert Wadepohl; Lutz H. Gade

doi:10.1039/C2CC17594K

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Stitching together SN_x units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite†

Thorsten Gehrmann,^a Matthias Kruck,^a Hubert Wadepohl^a and Lutz H. Gade*^a

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* Corresponding authors

^a Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
E-mail: lutz.gade@uni-hd.de

Abstract

Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN₂(N–N) unit.

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Article information

DOI: https://doi.org/10.1039/C2CC17594K
Article type: Communication
Submitted: 05 Dec 2011
Accepted: 06 Jan 2012
First published: 25 Jan 2012

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Chem. Commun., 2012,48, 2397-2399

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Stitching together SN_x units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

T. Gehrmann, M. Kruck, H. Wadepohl and L. H. Gade, Chem. Commun., 2012, 48, 2397 DOI: 10.1039/C2CC17594K

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