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Issue 18, 2012
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Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

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Abstract

Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN2(N–N) unit.

Graphical abstract: Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

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Submitted
05 Dec 2011
Accepted
06 Jan 2012
First published
25 Jan 2012

Chem. Commun., 2012,48, 2397-2399
Article type
Communication

Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

T. Gehrmann, M. Kruck, H. Wadepohl and L. H. Gade, Chem. Commun., 2012, 48, 2397
DOI: 10.1039/C2CC17594K

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