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Issue 30, 2012
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Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes

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Abstract

The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl[double bond, length as m-dash]PMes*)2 reacts with L2M(CO)4 (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me2SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom.

Graphical abstract: Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes

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Article information


Submitted
02 Dec 2011
Accepted
17 Feb 2012
First published
20 Feb 2012

Chem. Commun., 2012,48, 3629-3631
Article type
Communication

Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes

D. Matioszek, T. Kocsor, A. Castel, G. Nemes, J. Escudié and N. Saffon, Chem. Commun., 2012, 48, 3629
DOI: 10.1039/C2CC17551G

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