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Issue 15, 2012
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Cu-catalyzed asymmetric [3+2] cycloaddition of α-iminoamides with activated olefins

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Abstract

A variety of 2-amido pyrrolidines, including Weinreb-type amides, have been prepared with very high exo diastereoselectivity and enantioselectivitiy in the reaction of α-iminoamides with activated alkenes catalyzed by CuI–Segphos ligands.

Graphical abstract: Cu-catalyzed asymmetric [3+2] cycloaddition of α-iminoamides with activated olefins

  • This article is part of the themed collection: Chirality
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Publication details

The article was received on 17 Nov 2011, accepted on 23 Dec 2011 and first published on 04 Jan 2012


Article type: Communication
DOI: 10.1039/C2CC17149J
Citation: Chem. Commun., 2012,48, 2149-2151

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    Cu-catalyzed asymmetric [3+2] cycloaddition of α-iminoamides with activated olefins

    M. González-Esguevillas, J. Adrio and J. C. Carretero, Chem. Commun., 2012, 48, 2149
    DOI: 10.1039/C2CC17149J

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