Issue 11, 2012

Rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal alkenes

Abstract

An annulation via tandem rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal olefins followed by C–N bond formation is disclosed. A N-substituted quaternary center is formed during the reaction thus providing efficient access to a series of 3,3-disubstituted isoindolinones.

Graphical abstract: Rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal alkenes

Supplementary files

Article information

Article type
Communication
Submitted
09 Nov 2011
Accepted
26 Nov 2011
First published
01 Dec 2011

Chem. Commun., 2012,48, 1674-1676

Rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal alkenes

C. Zhu and J. R. Falck, Chem. Commun., 2012, 48, 1674 DOI: 10.1039/C2CC16963K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements