Issue 15, 2012
From the journal:

Chemical Communications

Unusual group migration and C(sp3)–H activation leading to stable metallacycles in the reactions of Cp*IrS2C2B10H10 and aryl azides†

Wei Zhong,a   Mingshi Xie,a   Qibai Jiang,a   Yizhi Lia  and  Hong Yan*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China
E-mail: hyan1965@nju.edu.cn
Fax: +86-25-83314502

Abstract

The thermal or photochemical reactions of Cp*IrS2C2B10H10 (1) and aryl azides lead to C–C coupling via C(sp3)–H activation in 2 as well as the formation of C–S bonds and new-type SSN pincer ligands in 3–8 through ortho-substituted electron-withdrawing group migration over an aryl ring.

Graphical abstract: Unusual group migration and C(sp3)–H activation leading to stable metallacycles in the reactions of Cp*IrS2C2B10H10 and aryl azides

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Article information

DOI
https://doi.org/10.1039/C2CC16943F
Article type
Communication
Submitted
09 Nov 2011
Accepted
15 Dec 2011
First published
13 Jan 2012

Chem. Commun., 2012,48, 2152-2154

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Unusual group migration and C(sp3)–H activation leading to stable metallacycles in the reactions of Cp*IrS2C2B10H10 and aryl azides

W. Zhong, M. Xie, Q. Jiang, Y. Li and H. Yan, Chem. Commun., 2012, 48, 2152 DOI: 10.1039/C2CC16943F

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