Issue 13, 2012
From the journal:

Chemical Communications

Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates†

David Rosaa  and  Arturo Orellana*a  

* Corresponding authors

a Department of Chemistry, York University, 4700 Keele Street, Toronto, ON, Canada
E-mail: aorellan@yorku.ca
Fax: +1 416 736 5936
Tel: +1 416 736 2100 ext 70760

Abstract

A palladium-catalysed, tandem cyclopropanol rearrangement and direct arylation approach for the synthesis of 1-indanones is reported. The reaction is generally high yielding, uses oxygen as the terminal oxidant and tolerates a range of functional groups on the aryl ring.

Graphical abstract: Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

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Article information

DOI
https://doi.org/10.1039/C2CC16758A
Article type
Communication
Submitted
01 Nov 2011
Accepted
10 Dec 2011
First published
12 Dec 2011

Chem. Commun., 2012,48, 1922-1924

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Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

D. Rosa and A. Orellana, Chem. Commun., 2012, 48, 1922 DOI: 10.1039/C2CC16758A

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