Issue 35, 2012
From the journal:

Chemical Communications

A zinc(ii) directed triple-stranded helicate incorporating a nine membered metallamacrocycle: supramolecular cylinders mimicking P1 nuclease†

Rakesh K. Mishra,a   K. K. Upadhyay,*a   Sachin Shuklab  and  R. Mishrab  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi-221005, India
E-mail: drkaushalbhu@yahoo.co.in, kku@bhu.ac.in
Fax: +91 542 236 8127
Tel: +91 542 670 2488

b Department of Zoology, Faculty of Science, Banaras Hindu University, Varanasi-221005, India
Tel: +91 542 670 2505

Abstract

We report herein the first small molecule based self-assembled fluorescent trinuclear Zn(II) supramolecular cylindrical motif as a structural and functional model of the active site of P1 nuclease. The DNA binding of the same was investigated through UV-Vis, fluorescence and circular dichroism studies.

Graphical abstract: A zinc(ii) directed triple-stranded helicate incorporating a nine membered metallamacrocycle: supramolecular cylinders mimicking P1 nuclease

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Article information

DOI
https://doi.org/10.1039/C2CC00094F
Article type
Communication
Submitted
05 Jan 2012
Accepted
01 Mar 2012
First published
05 Mar 2012

Chem. Commun., 2012,48, 4238-4240

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A zinc(II) directed triple-stranded helicate incorporating a nine membered metallamacrocycle: supramolecular cylinders mimicking P1 nuclease

R. K. Mishra, K. K. Upadhyay, S. Shukla and R. Mishra, Chem. Commun., 2012, 48, 4238 DOI: 10.1039/C2CC00094F

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