Issue 5, 2012
From the journal:

Chemical Communications

Temperature-directed structural recurrence in low-symmetric Co(ii) complexes and nanocrystals†

Yan-Yan Yin,a   Xiao-Yan Chen,a   Xiao-Chang Cao,a   Wei Shia  and  Peng Cheng*a  

* Corresponding authors

a Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Nankai University, Tianjin 300071, China
E-mail: pcheng@nankai.edu.cn

Abstract

Low-symmetric complexes {[Co(μ2-L)(H2O)2]·H2O}n (1) and {[Co(μ3-L)(H2O)]·0.5H2O}n (2) and corresponding nanocrystals were obtained, which exhibit structural recurrence behaviour at various temperatures as well as changes of chiral, nonlinear optical and ferroelectric properties.

Graphical abstract: Temperature-directed structural recurrence in low-symmetric Co(ii) complexes and nanocrystals

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Article information

DOI
https://doi.org/10.1039/C1CC16336A
Article type
Communication
Submitted
12 Oct 2011
Accepted
17 Nov 2011
First published
17 Nov 2011

Chem. Commun., 2012,48, 705-707

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Temperature-directed structural recurrence in low-symmetric Co(II) complexes and nanocrystals

Y. Yin, X. Chen, X. Cao, W. Shi and P. Cheng, Chem. Commun., 2012, 48, 705 DOI: 10.1039/C1CC16336A

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