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Issue 10, 2012

The unique rht-MOF platform, ideal for pinpointing the functionalization and CO2 adsorption relationship

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Abstract

The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO2 uptake in the resultant rht-MOF.

Graphical abstract: The unique rht-MOF platform, ideal for pinpointing the functionalization and CO2 adsorption relationship

Supplementary files

Article information


Submitted
25 Sep 2011
Accepted
03 Nov 2011
First published
28 Nov 2011

Chem. Commun., 2012,48, 1455-1457
Article type
Communication

The unique rht-MOF platform, ideal for pinpointing the functionalization and CO2 adsorption relationship

R. Luebke, J. F. Eubank, A. J. Cairns, Y. Belmabkhout, L. Wojtas and M. Eddaoudi, Chem. Commun., 2012, 48, 1455 DOI: 10.1039/C1CC15962C

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