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Issue 13, 2012
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Supramolecular polymorphism of the 1 : 1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt

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Abstract

The tetrahedral arrangement of hydrogen bonding donor and acceptor groups is used to rationalise the design of a diamondoid network; however, a single proton transfer renders the four sites inequivalent, and results in two polymorphs of the title molecular salt utilizing similar intermolecular synthons.

Graphical abstract: Supramolecular polymorphism of the 1 : 1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt

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Publication details

The article was received on 21 Sep 2011, accepted on 18 Nov 2011 and first published on 02 Dec 2011


Article type: Communication
DOI: 10.1039/C1CC15849J
Citation: Chem. Commun., 2012,48, 1883-1885

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    Supramolecular polymorphism of the 1 : 1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt

    A. Lemmerer, J. Bernstein and M. A. Spackman, Chem. Commun., 2012, 48, 1883
    DOI: 10.1039/C1CC15849J

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