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Issue 10, 2012

A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

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Abstract

An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each “half-SMM” composing this molecular cluster pair.

Graphical abstract: A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

Supplementary files

Article information


Submitted
14 Sep 2011
Accepted
19 Oct 2011
First published
18 Nov 2011

Chem. Commun., 2012,48, 1413-1415
Article type
Communication

A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

J. S. Costa, L. A. Barrios, G. A. Craig, S. J. Teat, F. Luis, O. Roubeau, M. Evangelisti, A. Camón and G. Aromí, Chem. Commun., 2012, 48, 1413 DOI: 10.1039/C1CC15682A

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