Issue 9, 2012

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

Abstract

Ligand modification transforms a polyoxometalate-anchored cubane-type [MnIII3MnIVO4] core into a centrosymmetric [MnIII6MnIVO8] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn4O4] cubane-based single-molecule magnets.

Graphical abstract: A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

Supplementary files

Article information

Article type
Communication
Submitted
06 Sep 2011
Accepted
28 Oct 2011
First published
18 Nov 2011

Chem. Commun., 2012,48, 1218-1220

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

X. Fang, P. Kögerler, M. Speldrich, H. Schilder and M. Luban, Chem. Commun., 2012, 48, 1218 DOI: 10.1039/C1CC15520B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements