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Issue 10, 2012
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Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry?

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Abstract

The mixed-valent cerium(III/IV) oxide clusters {Ce10} and {Ce22}, derived from condensation reactions of cerium carboxylate coordination polymers, exhibit molecular growth tendencies similar to those of ‘classical’ group V and VI polyoxometalates, but with increasing nuclearity approach the structure of the parental oxide, CeO2.

Graphical abstract: Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry?

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Supplementary files

Article information


Submitted
31 Jul 2011
Accepted
20 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2012,48, 1499-1501
Article type
Communication

Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry?

I. L. Malaestean, A. Ellern, S. Baca and P. Kögerler, Chem. Commun., 2012, 48, 1499
DOI: 10.1039/C1CC14725K

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