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Issue 10, 2012

Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

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Abstract

[Cp2Dy(thf)(μ-Cl)]2 (2) was synthesized from [Cp2Dy(μ-Cl)]n, which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased.

Graphical abstract: Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

Supplementary files

Article information


Submitted
28 Jul 2011
Accepted
27 Aug 2011
First published
16 Sep 2011

Chem. Commun., 2012,48, 1508-1510
Article type
Communication

Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

S. A. Sulway, R. A. Layfield, F. Tuna, W. Wernsdorfer and R. E. P. Winpenny, Chem. Commun., 2012, 48, 1508 DOI: 10.1039/C1CC14643B

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