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Issue 10, 2012

Iron-catalysed, hydride-mediated reductive cross-coupling of vinyl halides and Grignard reagents

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Abstract

An iron-catalysed, hydride-mediated reductive cross-coupling reaction has been developed for the preparation of alkanes. Using a bench-stable iron(II) pre-catalyst, reductive cross-coupling of vinyl iodides, bromides and chlorides with aryl- and alkyl Grignard reagents successfully gave the products of formal sp3–sp3 cross-coupling reactions.

Graphical abstract: Iron-catalysed, hydride-mediated reductive cross-coupling of vinyl halides and Grignard reagents

Supplementary files

Article information


Submitted
28 Jul 2011
Accepted
14 Oct 2011
First published
31 Oct 2011

Chem. Commun., 2012,48, 1580-1582
Article type
Communication

Iron-catalysed, hydride-mediated reductive cross-coupling of vinyl halides and Grignard reagents

B. A. F. Le Bailly, M. D. Greenhalgh and S. P. Thomas, Chem. Commun., 2012, 48, 1580 DOI: 10.1039/C1CC14622J

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