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Issue 10, 2012
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Aminoborylation/Suzuki–Miyaura tandem cross coupling of aryl iodides as efficient and selective synthesis of unsymmetrical biaryls

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Abstract

Sequential borylation of a first aryl iodide using a dialkylaminoborane followed by a Suzuki–Miyaura cross coupling of second aryl iodide ended up with an efficient, selective and practical synthesis of unsymmetrical biaryls. This tandem coupling shows a wide range of applicability.

Graphical abstract: Aminoborylation/Suzuki–Miyaura tandem cross coupling of aryl iodides as efficient and selective synthesis of unsymmetrical biaryls

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Article information


Submitted
27 Jul 2011
Accepted
20 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2012,48, 1553-1555
Article type
Communication

Aminoborylation/Suzuki–Miyaura tandem cross coupling of aryl iodides as efficient and selective synthesis of unsymmetrical biaryls

L. Marciasini, N. Richy, M. Vaultier and M. Pucheault, Chem. Commun., 2012, 48, 1553
DOI: 10.1039/C1CC14605J

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