Issue 10, 2012
From the journal:

Chemical Communications

Calix[4]arene-supported rare earth octahedra†‡

Sergio Sanz,a   Ruaraidh D. McIntosh,b   Christine M. Beavers,c   Simon J. Teat,c   Marco Evangelisti,d   Euan K. Brechin*a  and  Scott J. Dalgarno*b  

* Corresponding authors

a EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, Scotland
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: + 44 (0)131 650 6453
Tel: + 44 (0)131 650 7545

b School of Engineering and Physical Sciences–Chemistry, Heriot–Watt University, Riccarton, Edinburgh, Scotland
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: + 44(0) 131 451 3180
Tel: + 44 (0)131 451 8025

c Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS 6R2100, Berkeley, USA

d Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain
E-mail: evange@unizar.es
Fax: + 34 976 761 229
Tel: + 34 876 553 342

Abstract

A series of calix[4]arene-supported LnIII6 clusters have been synthesised under facile bench top conditions. The magnetic and structural properties of these clusters are reported, the latter suggesting that the LnIII-calix[4]arene moiety may be used for the construction of other assemblies in a manner akin to that for the MnIII-calix[4]arene analogue.

Graphical abstract: Calix[4]arene-supported rare earth octahedra

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Article information

DOI
https://doi.org/10.1039/C1CC14603C
Article type
Communication
Submitted
27 Jul 2011
Accepted
18 Aug 2011
First published
09 Sep 2011

Chem. Commun., 2012,48, 1449-1451

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Calix[4]arene-supported rare earth octahedra

S. Sanz, R. D. McIntosh, C. M. Beavers, S. J. Teat, M. Evangelisti, E. K. Brechin and S. J. Dalgarno, Chem. Commun., 2012, 48, 1449 DOI: 10.1039/C1CC14603C

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