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Issue 10, 2012
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Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

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Abstract

A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.

Graphical abstract: Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

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Publication details

The article was received on 24 Dec 2010, accepted on 21 Mar 2011 and first published on 11 Apr 2011


Article type: Communication
DOI: 10.1039/C0CC05777K
Citation: Chem. Commun., 2012,48, 1428-1430

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    Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

    L. Bernardi, E. Indrigo, S. Pollicino and A. Ricci, Chem. Commun., 2012, 48, 1428
    DOI: 10.1039/C0CC05777K

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