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Issue 10, 2012

Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

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Abstract

A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.

Graphical abstract: Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

Supplementary files

Article information


Submitted
24 Dec 2010
Accepted
21 Mar 2011
First published
11 Apr 2011

Chem. Commun., 2012,48, 1428-1430
Article type
Communication

Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

L. Bernardi, E. Indrigo, S. Pollicino and A. Ricci, Chem. Commun., 2012, 48, 1428 DOI: 10.1039/C0CC05777K

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