Issue 41, 2011

New insight into solid-state molecular dynamics: mechanochemical synthesis of azobenzene/triphenylphosphine palladacycles

Abstract

Solid-state reactions of dicyclopalladated azobenzenes and triphenylphosphine lead to the thermodynamically favorable bridged complexes. It was demonstrated for the first time that very complex molecular dynamics involving a series of structural transformations is also feasible in the solid state.

Graphical abstract: New insight into solid-state molecular dynamics: mechanochemical synthesis of azobenzene/triphenylphosphine palladacycles

Supplementary files

Article information

Article type
Communication
Submitted
29 Aug 2011
Accepted
08 Sep 2011
First published
20 Sep 2011

Chem. Commun., 2011,47, 11543-11545

New insight into solid-state molecular dynamics: mechanochemical synthesis of azobenzene/triphenylphosphine palladacycles

D. Cinčić, M. Juribašić, D. Babić, K. Molčanov, P. Šket, J. Plavec and M. Ćurić, Chem. Commun., 2011, 47, 11543 DOI: 10.1039/C1CC15377C

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