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Issue 41, 2011
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Asymmetric Brønsted acid catalyzed carbonyl activation – organocatalytic domino electrocyclization–halogenation reaction

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Abstract

A highly efficient Brønsted acid catalyzed enantioselective Nazarov cyclization–bromination reaction has been developed. The protocol gives access to highly functionalized trans-4,5-substituted 5-bromocyclopentenone derivatives in good yields and with excellent enantioselectivities.

Graphical abstract: Asymmetric Brønsted acid catalyzed carbonyl activation – organocatalytic domino electrocyclization–halogenation reaction

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Publication details

The article was received on 25 Aug 2011, accepted on 25 Aug 2011 and first published on 05 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC15289K
Citation: Chem. Commun., 2011,47, 11450-11452

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    Asymmetric Brønsted acid catalyzed carbonyl activation – organocatalytic domino electrocyclization–halogenation reaction

    M. Rueping and W. Ieawsuwan, Chem. Commun., 2011, 47, 11450
    DOI: 10.1039/C1CC15289K

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