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Issue 42, 2011
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C–N Bond formation vialigand-induced nucleophilicity at a coordinated triamidoamine ligand

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Abstract

Reaction of (N3N)ZrX complexes (X = amido, Cl, CH3) with carbodiimide substrates results in insertion into an Zr–N bond of the triamidoamine ligand rather than the Zr–X bond as has been observed for related (N3N)ZrX complexes (X = PR2, AsR2).

Graphical abstract: C–N Bond formation via ligand-induced nucleophilicity at a coordinated triamidoamine ligand

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Publication details

The article was received on 19 Aug 2011, accepted on 12 Sep 2011 and first published on 28 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC15179G
Chem. Commun., 2011,47, 11769-11771

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    C–N Bond formation via ligand-induced nucleophilicity at a coordinated triamidoamine ligand

    A. F. Maddox, K. A. Erickson, J. M. Tanski and R. Waterman, Chem. Commun., 2011, 47, 11769
    DOI: 10.1039/C1CC15179G

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