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Issue 42, 2011
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Regio- and stereoselective synthesis of 1,4-dienes

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Abstract

Titanocene(II)-promoted cross-coupling between (Z)-alkenyl methyl sulfones and terminal allenes produced 1,4-dienes regioselectively via the formation of 2-alkylidenetitanacyclopentanes. Preferential formation of E,Z-dienes was observed in the reaction using aryl-, amino-, and phosphinylallenes.

Graphical abstract: Regio- and stereoselective synthesis of 1,4-dienes

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The article was received on 02 Aug 2011, accepted on 05 Sep 2011 and first published on 15 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14765J
Chem. Commun., 2011,47, 11639-11640

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    Regio- and stereoselective synthesis of 1,4-dienes

    S. Oishi, K. Hatano, A. Tsubouchi and T. Takeda, Chem. Commun., 2011, 47, 11639
    DOI: 10.1039/C1CC14765J

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