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Issue 36, 2011
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Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

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Abstract

Catalytic addition of silylacetylenes to α,β-unsaturated ketones proceeded in the presence of a cobalt complex coordinated with a bisphosphine ligand to give high yields of β-alkynylketones.

Graphical abstract: Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

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Publication details

The article was received on 08 Jul 2011, accepted on 27 Jul 2011 and first published on 10 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC14098A
Chem. Commun., 2011,47, 10142-10144

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    Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

    T. Nishimura, T. Sawano, K. Ou and T. Hayashi, Chem. Commun., 2011, 47, 10142
    DOI: 10.1039/C1CC14098A

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