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Issue 35, 2011
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An unusual reaction of α-alkoxyphosphonium salts with Grignard reagents under an O2 atmosphere

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Abstract

An unusual and novel reaction of α-alkoxyphosphonium salts, generated from O,O-acetals and Ph3P, with Grignard reagents under an O2 atmosphere afforded alcohols in moderate to high yields. It was clarified by isotopic labelling experiments that the reaction proceeded via a novel radical pathway.

Graphical abstract: An unusual reaction of α-alkoxyphosphonium salts with Grignard reagents under an O2 atmosphere

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Publication details

The article was received on 01 Jul 2011, accepted on 19 Jul 2011 and first published on 04 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13919C
Citation: Chem. Commun., 2011,47, 9894-9896
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    An unusual reaction of α-alkoxyphosphonium salts with Grignard reagents under an O2 atmosphere

    H. Fujioka, A. Goto, K. Otake, O. Kubo, Y. Sawama and T. Maegawa, Chem. Commun., 2011, 47, 9894
    DOI: 10.1039/C1CC13919C

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