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Issue 39, 2011
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Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation

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Abstract

This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(III)-hydroperoxo species. We show that in contrast to their heme counterparts the nonheme iron(III)-hydroperoxo complexes are catalytically much more active and even more so than nonheme iron(IV)-oxo species.

Graphical abstract: Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation

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Publication details

The article was received on 24 Jun 2011, accepted on 24 Aug 2011 and first published on 09 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC13775A
Chem. Commun., 2011,47, 11044-11046

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    Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation

    A. K. Vardhaman, C. V. Sastri, D. Kumar and S. P. de Visser, Chem. Commun., 2011, 47, 11044
    DOI: 10.1039/C1CC13775A

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