Issue 36, 2011

Controlling stereoselectivity of solid-state photoreactions by co-crystal formation

Abstract

An external heavy-atom effect in crystals was found to influence the reaction path of the photocyclization of cyclohexenones drastically, and that was successfully applied to control the cis–trans stereochemistry of the reaction by making co-crystals of heavy-atom containing and non-containing analogues in various ratios.

Graphical abstract: Controlling stereoselectivity of solid-state photoreactions by co-crystal formation

Supplementary files

Article information

Article type
Communication
Submitted
13 Jun 2011
Accepted
18 Jul 2011
First published
10 Aug 2011

Chem. Commun., 2011,47, 10097-10099

Controlling stereoselectivity of solid-state photoreactions by co-crystal formation

R. Sekiya and R. Kuroda, Chem. Commun., 2011, 47, 10097 DOI: 10.1039/C1CC13484A

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