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Issue 33, 2011
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Homochiral 3D metal–organic frameworks from chiral 1D rods: 6-way helical packing

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Abstract

The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is sensitively dependent on the dimension of SBBs. In addition, we were able to identify a new plywood-like network from ligand 2H2 exhibiting an unprecedented six-way chiral helical packing motif, which extends the list of invariant rod packings.

Graphical abstract: Homochiral 3D metal–organic frameworks from chiral 1D rods: 6-way helical packing

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Publication details

The article was received on 18 May 2011, accepted on 29 Jun 2011 and first published on 20 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12908B
Chem. Commun., 2011,47, 9402-9404

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    Homochiral 3D metal–organic frameworks from chiral 1D rods: 6-way helical packing

    S. M. Shin, D. Moon, K. S. Jeong, J. Kim, P. K. Thallapally and N. Jeong, Chem. Commun., 2011, 47, 9402
    DOI: 10.1039/C1CC12908B

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