Issue 32, 2011
From the journal:

Chemical Communications

A novel low density metal–organic framework with pcu topology by dendritic ligand†

Jiangtao Jia,a   Fuxing Sun,a   Qianrong Fang,a   Xiaoqiang Liang,a   Kun Cai,a   Zheng Bian,*b   Huijun Zhao,c   Lianxun Gaob  and  Guangshan Zhu*a  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
E-mail: zhugs@jlu.edu.cn
Fax: +86-431-85168331
Tel: +86-431-85168887

b State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: bianzh@ciac.jl.cn
Fax: +86-431-85697831
Tel: +86-431-85262265

c Griffith School of Environment, Griffith University, Queensland, Australia

Abstract

A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn4O(CO2)6 units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H2 uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.

Graphical abstract: A novel low density metal–organic framework with pcu topology by dendritic ligand

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Article information

DOI
https://doi.org/10.1039/C1CC12891D
Article type
Communication
Submitted
17 May 2011
Accepted
01 Jul 2011
First published
13 Jul 2011

Chem. Commun., 2011,47, 9167-9169

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A novel low density metal–organic framework with pcu topology by dendritic ligand

J. Jia, F. Sun, Q. Fang, X. Liang, K. Cai, Z. Bian, H. Zhao, L. Gao and G. Zhu, Chem. Commun., 2011, 47, 9167 DOI: 10.1039/C1CC12891D

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