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Issue 32, 2011
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Water-assisted assembly of (E)-arylvinylpyridine hydrochlorides: effective substrates for solid-state [2+2] photodimerization

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Abstract

Water molecules assist the assembly of (E)-arylvinylpyridine hydrochlorides in a head-to-tail and face-to-face fashion by way of N–H⋯O hydrogen bonds in combination with cation–π interactions between the pyridinium and aromatic rings. Photolysis of the pyridinium salt hydrates provided synHT dimers in high yields.

Graphical abstract: Water-assisted assembly of (E)-arylvinylpyridine hydrochlorides: effective substrates for solid-state [2+2] photodimerization

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Publication details

The article was received on 03 May 2011, accepted on 20 Jun 2011 and first published on 08 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12572A
Chem. Commun., 2011,47, 9143-9145

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    Water-assisted assembly of (E)-arylvinylpyridine hydrochlorides: effective substrates for solid-state [2+2] photodimerization

    S. Yamada and Y. Nojiri, Chem. Commun., 2011, 47, 9143
    DOI: 10.1039/C1CC12572A

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