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Issue 27, 2011
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Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor

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Abstract

Catalytic trans-selective hydrogermylation of terminal and internal alkynes was attained by a methyliron complex, CpFe(CO)2(Me), and a bis(germyl)hydridoiron(IV) complex as a catalyst precursor. The structures of (Z)-triphenyl-(2-phenylethenyl)germane and the bis(germyl)hydridoiron(IV) complexes CpFe(CO)(H)(GeR3)2 (R = Et, Ph) were confirmed by single crystal X-ray diffraction studies.

Graphical abstract: Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor

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Publication details

The article was received on 30 Apr 2011, accepted on 24 May 2011 and first published on 06 Jun 2011


Article type: Communication
DOI: 10.1039/C1CC12530C
Citation: Chem. Commun., 2011,47, 7854-7856

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    Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor

    M. Itazaki, M. Kamitani and H. Nakazawa, Chem. Commun., 2011, 47, 7854
    DOI: 10.1039/C1CC12530C

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