Issue 39, 2011

Photosensitizing catalysis of the B12 complex without an additional photosensitizer

Abstract

A cobalamin derivative, heptamethyl cobyrinate perchlorate, was activated by UV light irradiation to form a Co(I) species in the presence of triethanolamine and used for a dechlorination reaction, and this photochemical reaction was accelerated in an ionic liquid.

Graphical abstract: Photosensitizing catalysis of the B12 complex without an additional photosensitizer

Supplementary files

Article information

Article type
Communication
Submitted
28 Apr 2011
Accepted
31 May 2011
First published
13 Jun 2011

Chem. Commun., 2011,47, 10921-10923

Photosensitizing catalysis of the B12 complex without an additional photosensitizer

H. Shimakoshi, L. Li, M. Nishi and Y. Hisaeda, Chem. Commun., 2011, 47, 10921 DOI: 10.1039/C1CC12482J

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