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Issue 30, 2011
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Novel heterobimetallic ruthenium(III)–cobalt(II) compounds constructed from trans-[RuIII(Q)2(CN)2] (Q = 8-quinolinolato): synthesis, structures and magnetic properties

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Abstract

Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(III) building block, [RuIII(Q)2(CN)2]. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.

Graphical abstract: Novel heterobimetallic ruthenium(iii)–cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]− (Q = 8-quinolinolato): synthesis, structures and magnetic properties

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Publication details

The article was received on 27 Apr 2011, accepted on 21 Jun 2011 and first published on 02 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12446C
Chem. Commun., 2011,47, 8694-8696

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    Novel heterobimetallic ruthenium(III)–cobalt(II) compounds constructed from trans-[RuIII(Q)2(CN)2] (Q = 8-quinolinolato): synthesis, structures and magnetic properties

    J. Xiang, L. Jia, W. Man, K. Qian, S. Yiu, G. Lee, S. Peng, S. Gao and T. Lau, Chem. Commun., 2011, 47, 8694
    DOI: 10.1039/C1CC12446C

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