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Issue 32, 2011
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A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

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Abstract

A series of mononuclear MnII, MnIII, and MnIV complexes was prepared using a single tripodal ligand (H3L). Addition of a cation (NH4+, K+, Na+) to [MnIIIL] showed a pronounced effect on the redox potentials. Different variants of Jahn–Teller distortion, axial elongation and compression, were observed in the MnIII complexes.

Graphical abstract: A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

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The article was received on 26 Apr 2011, accepted on 24 Jun 2011 and first published on 13 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12418H
Chem. Commun., 2011,47, 9149-9151

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    A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

    Y. Sunatsuki, Y. Kishima, T. Kobayashi, T. Yamaguchi, T. Suzuki, M. Kojima, J. Krzystek and M. R. Sundberg, Chem. Commun., 2011, 47, 9149
    DOI: 10.1039/C1CC12418H

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