Issue 29, 2011
From the journal:

Chemical Communications

More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs†

Hanh V. Ly,a   Jani Moilanen,b   Heikki M. Tuononen,b   Masood Parveza  and  Roland Roesler*a  

* Corresponding authors

a Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, Canada
E-mail: roesler@ucalgary.ca
Fax: +1 (403) 289 9488
Tel: +1 (403) 220 5366

b Department of Chemistry, University of Jyväskylä, P.O. Box 35, FIN-40014 Jyväskylä, Finland
Fax: +358 (14) 260 2501
Tel: +358 (14) 260 2618

Abstract

Ruthenium and iron sandwich complexes incorporating cyclopentadienyl analogs with CB2N2− skeletons were characterized. Electrochemical measurements supported by computational studies revealed that in combination with larger metal ions such as Ru the CB2N2− ligand can be more electron-rich than its organic counterpart.

Graphical abstract: More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs

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Article information

DOI
https://doi.org/10.1039/C1CC12281A
Article type
Communication
Submitted
19 Apr 2011
Accepted
05 Jun 2011
First published
24 Jun 2011

Chem. Commun., 2011,47, 8391-8393

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More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs

H. V. Ly, J. Moilanen, H. M. Tuononen, M. Parvez and R. Roesler, Chem. Commun., 2011, 47, 8391 DOI: 10.1039/C1CC12281A

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