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Issue 25, 2011
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A regioselective synthesis of poly-substituted aryl triflones through self-promoting three component reaction

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Abstract

In the absence of any additional catalysts, the reactions of (CF3SO)2CH2, aldehydes, and 1,3-dienes gave gem-bis(triflyl)cyclohexenes in excellent yields with high regioselectivity. gem-Bis(triflyl)cyclohexene products can be easily converted to the corresponding aryl trifluoromethyl sulfones.

Graphical abstract: A regioselective synthesis of poly-substituted aryl triflones through self-promoting three component reaction

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Supplementary files

Article information


Submitted
12 Apr 2011
Accepted
11 May 2011
First published
24 May 2011

Chem. Commun., 2011,47, 7245-7247
Article type
Communication

A regioselective synthesis of poly-substituted aryl triflones through self-promoting three component reaction

H. Yanai, M. Fujita and T. Taguchi, Chem. Commun., 2011, 47, 7245 DOI: 10.1039/C1CC12093J

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