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Issue 25, 2011
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Highly enantioselective organocascade intermolecular iminium/enamineMichael addition on enals

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Abstract

An unprecedented intermolecular iminium/enamine Michael addition on enals has been developed by taking advantage of the high reactivity of vinyl sulfones. This powerful organocascade allows for the rapid construction of attractive synthons in high enantioselectivities (typically 99% ee).

Graphical abstract: Highly enantioselective organocascade intermolecular iminium/enamine Michael addition on enals

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Article information


Submitted
07 Apr 2011
Accepted
27 Apr 2011
First published
23 May 2011

Chem. Commun., 2011,47, 7212-7214
Article type
Communication

Highly enantioselective organocascade intermolecular iminium/enamine Michael addition on enals

A. Quintard and A. Alexakis, Chem. Commun., 2011, 47, 7212
DOI: 10.1039/C1CC11967B

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