Issue 27, 2011

Access to unusual polycyclic spiro-enones from 2,2′-bis(allyloxy)-1,1′-binaphthyls using Grubbs'catalysts: an unprecedented one-pot RCM/Claisen sequence

Abstract

Treatment of 2,2′-bis(allyloxy)-1,1′-binaphthyls with the first-generation Grubbs' carbene under MW-irradiation results in the formation of new polycyclic spiro-enones through an unprecedented RCM/Claisen sequence.

Graphical abstract: Access to unusual polycyclic spiro-enones from 2,2′-bis(allyloxy)-1,1′-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

Supplementary files

Article information

Article type
Communication
Submitted
04 Apr 2011
Accepted
24 May 2011
First published
03 Jun 2011

Chem. Commun., 2011,47, 7866-7868

Access to unusual polycyclic spiro-enones from 2,2′-bis(allyloxy)-1,1′-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

E. Piedra, J. Francos, N. Nebra, F. J. Suárez, J. Díez and V. Cadierno, Chem. Commun., 2011, 47, 7866 DOI: 10.1039/C1CC11907A

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