Issue 24, 2011
From the journal:

Chemical Communications

“Clickable” pillar[5]arenes†

Tomoki Ogoshi,*a   Ryohei Shiga,a   Masayoshi Hashizumea  and  Tada-aki Yamagishia  

* Corresponding authors

a Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan
E-mail: ogoshi@t.kanazawa-u.ac.jp
Fax: +81-76-234-4800
Tel: +81-76-234-4775

Abstract

Introduction of bulky substituents such as benzyl and pyrenyl groups using click reactions inhibited or slowed the rotation of the units on the NMR chemical shift timescale. The perpyrenylated pillar[5]arene showed a thermally-responsive excimer emission, but a unit model of the perpyrenylated pillar[5]arene did not exhibit such a response.

Graphical abstract: “Clickable” pillar[5]arenes

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Article information

DOI
https://doi.org/10.1039/C1CC11864A
Article type
Communication
Submitted
01 Apr 2011
Accepted
20 Apr 2011
First published
23 May 2011

Chem. Commun., 2011,47, 6927-6929

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“Clickable” pillar[5]arenes

T. Ogoshi, R. Shiga, M. Hashizume and T. Yamagishi, Chem. Commun., 2011, 47, 6927 DOI: 10.1039/C1CC11864A

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