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Issue 27, 2011
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Divergent reactivity of α-oximino carbenoids: facile access to 2-isoxazolines and 2H-azirines

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Abstract

Mild catalytic reaction conditions for the synthesis of 2-isoxazolines and 2H-azirines have been developed via carbenoids derived from α-oximino diazo compounds. This has been utilized in the one-pot synthesis of pyrroles in the presence of 1,3-dicarbonyl compounds.

Graphical abstract: Divergent reactivity of α-oximino carbenoids: facile access to 2-isoxazolines and 2H-azirines

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Article information


Submitted
24 Mar 2011
Accepted
20 May 2011
First published
06 Jun 2011

Chem. Commun., 2011,47, 7848-7850
Article type
Communication

Divergent reactivity of α-oximino carbenoids: facile access to 2-isoxazolines and 2H-azirines

X. Qi, Y. Jiang and C. Park, Chem. Commun., 2011, 47, 7848
DOI: 10.1039/C1CC11683E

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