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Issue 18, 2011
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Pd(0)/Au(i) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(i)-complexes

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Abstract

A Pd(II)-catalyzed homo-coupling of Au(I)-aryls is reported. The reaction is driven by a Pd(0)/Au(I) redox reaction that generates a gold mirror and Pd(II), and illustrates one of the challenges for developing dual catalytic Au–Pd systems.

Graphical abstract: Pd(0)/Au(i) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(i)-complexes

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Supplementary files

Article information


Submitted
22 Feb 2011
Accepted
17 Mar 2011
First published
31 Mar 2011

Chem. Commun., 2011,47, 5172-5174
Article type
Communication

Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes

D. Weber and M. R. Gagné, Chem. Commun., 2011, 47, 5172
DOI: 10.1039/C1CC11055A

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