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Issue 17, 2011
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Metal–ligand bifunctional activation and transfer of N–H bonds

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Abstract

The concept of metal–ligand bifunctionality can be employed for an efficient activation of N–H bonds by well-defined ruthenium amido complexes. An enantioselective catalytic aza-Michael reaction was developed on the basis of this process, which gives rise to indoline β-amino acids.

Graphical abstract: Metal–ligand bifunctional activation and transfer of N–H bonds

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Publication details

The article was received on 20 Feb 2011, accepted on 10 Mar 2011 and first published on 24 Mar 2011


Article type: Communication
DOI: 10.1039/C1CC10999E
Chem. Commun., 2011,47, 4911-4913

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    Metal–ligand bifunctional activation and transfer of N–H bonds

    K. Muñiz, A. Lishchynskyi, J. Streuff, M. Nieger, E. C. Escudero-Adán and M. M. Belmonte, Chem. Commun., 2011, 47, 4911
    DOI: 10.1039/C1CC10999E

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