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Issue 21, 2011
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Nickel-iminophosphine-catalyzed [4+2] cycloaddition of enones with allenes: synthesis of highly substituted dihydropyrans

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Abstract

Enones were found to react with allenes intermolecularly in the presence of a catalytic amount of a nickel-iminophosphine complex to provide dihydropyrans via oxidative cyclization of an enone and Ni(0).

Graphical abstract: Nickel-iminophosphine-catalyzed [4+2] cycloaddition of enones with allenes: synthesis of highly substituted dihydropyrans

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Article information


Submitted
15 Feb 2011
Accepted
05 Apr 2011
First published
26 Apr 2011

Chem. Commun., 2011,47, 6150-6152
Article type
Communication

Nickel-iminophosphine-catalyzed [4+2] cycloaddition of enones with allenes: synthesis of highly substituted dihydropyrans

S. Sako, T. Kurahashi and S. Matsubara, Chem. Commun., 2011, 47, 6150
DOI: 10.1039/C1CC10890E

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