Issue 20, 2011

Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

Abstract

The halogen-bonded adduct between DABCO and two molecules of perfluorooctyl iodide (DABCO·(C8F17I)2) acts as a recyclable organocatalyst for the Morita–Baylis–Hillman reaction. This “supramolecular fluorous catalyst” is readily accessible and can be recovered by simple precipitation/filtration.

Graphical abstract: Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
14 Feb 2011
Accepted
28 Mar 2011
First published
15 Apr 2011

Chem. Commun., 2011,47, 5855-5857

Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

S. Dordonne, B. Crousse, D. Bonnet-Delpon and J. Legros, Chem. Commun., 2011, 47, 5855 DOI: 10.1039/C1CC10869G

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