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Issue 17, 2011
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Chiral (thio)phosphorodiamides as excellent hydrogen bond donor catalysts in the asymmetric Michael addition of 2-hydroxy-1,4-naphthoquione to nitroolefins

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Abstract

A novel type of bidentate hydrogen bond donor catalysts based on (thio)phosphorodiamides catalophore has been developed for the asymmetric Michael addition of 2-hydroxy-1,4-naphthoquione to nitroolefins, affording the corresponding adducts in high yields with excellent level of enantioselectivities (97– >99% ee).

Graphical abstract: Chiral (thio)phosphorodiamides as excellent hydrogen bond donor catalysts in the asymmetric Michael addition of 2-hydroxy-1,4-naphthoquione to nitroolefins

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Publication details

The article was received on 11 Feb 2011, accepted on 10 Mar 2011 and first published on 24 Mar 2011


Article type: Communication
DOI: 10.1039/C1CC10797F
Citation: Chem. Commun., 2011,47, 5034-5036
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    Chiral (thio)phosphorodiamides as excellent hydrogen bond donor catalysts in the asymmetric Michael addition of 2-hydroxy-1,4-naphthoquione to nitroolefins

    R. Wu, X. Chang, A. Lu, Y. Wang, G. Wu, H. Song, Z. Zhou and C. Tang, Chem. Commun., 2011, 47, 5034
    DOI: 10.1039/C1CC10797F

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