Issue 19, 2011
From the journal:

Chemical Communications

DMAP-catalyzed esterification of pentaerythritol-derivatized POMs: a new route for the functionalization of polyoxometalates†

Pingfan Wu,‡ab   Zicheng Xiao,‡b   Jin Zhang,b   Jian Hao,b   Jiake Chen,b   Panchao Yinb  and  Yongge Wei*bc  

* Corresponding authors

a School of Chemical & Environmental Engineering, Hubei University of Technology, Wuhan 430068, China

b Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: yonggewei@mail.tsinghua.edu.cn

c Key Laboratory of Cluster Science (Beijing Institute of Technology), Ministry of Education of China, Beijing 100081, P. R. China

Abstract

We have demonstrated that a pentaerythritol-derivatized hexavanadate can be easily esterified with acid anhydrides using 4-(N,N-dimethylamino)pyridine (DMAP) as a catalyst, which provides a convenient method for the functionalization of polyoxometalates.

Graphical abstract: DMAP-catalyzed esterification of pentaerythritol-derivatized POMs: a new route for the functionalization of polyoxometalates

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Article information

DOI
https://doi.org/10.1039/C1CC10650C
Article type
Communication
Submitted
01 Feb 2011
Accepted
21 Mar 2011
First published
05 Apr 2011

Chem. Commun., 2011,47, 5557-5559

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DMAP-catalyzed esterification of pentaerythritol-derivatized POMs: a new route for the functionalization of polyoxometalates

P. Wu, Z. Xiao, J. Zhang, J. Hao, J. Chen, P. Yin and Y. Wei, Chem. Commun., 2011, 47, 5557 DOI: 10.1039/C1CC10650C

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