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Issue 24, 2011
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Facile formation of a mesomeso linked porphyrin dimer catalyzed by a manganese(iv)–oxo porphyrin

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Abstract

A manganese(IV)–oxo porphyrin catalyzes C–C bond formation between zinc porphyrins at the meso-position with a two-electron oxidant to afford the mesomeso linked porphyrin dimer efficiently. The mesomeso linked dimer is formed via formation of the porphyrin radical cation, and the rate-determining step in the catalytic cycle is the formation of a manganese(IV)–oxo porphyrin with a two-electron oxidant.

Graphical abstract: Facile formation of a meso–meso linked porphyrin dimer catalyzed by a manganese(iv)–oxo porphyrin

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Article information


Submitted
31 Jan 2011
Accepted
19 Apr 2011
First published
10 May 2011

Chem. Commun., 2011,47, 6804-6806
Article type
Communication

Facile formation of a mesomeso linked porphyrin dimer catalyzed by a manganese(IV)–oxo porphyrin

A. Takai, B. Habermeyer and S. Fukuzumi, Chem. Commun., 2011, 47, 6804
DOI: 10.1039/C1CC10608B

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